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I'm interested in studying the solubility of water molecules in toluene.

I already know that some water can dissolve in toluene. I've also done some calculations at DFT level using the C-PCM solvation model, but unfortunately, the DFT theory does not correctly describe all water's properties.

Is there somebody that has studied this phenomenon? I was able to find only toluene-in-water system.

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    $\begingroup$ Mutual Solubility Measurements of Hydrocarbon–Water Systems Containing Benzene, Toluene, and 3-Methylpentane is available from ACS at J. Chem. Eng. Data 2008, 53, 1, 165–174 Publication Date:November 21, 2007 doi.org/10.1021/je700449z but apparently it will cost you. $\endgroup$
    – James Gaidis
    May 24 at 14:21
  • $\begingroup$ @JamesGaidis - depends if their institution has access. I get the full article with no issues. I'm sure a librarian can get it for them if the library doesn't have it. $\endgroup$
    – Jon Custer
    May 24 at 16:28

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