First off, be aware that oxidative addition occurs by several mechanisms which are governed by different factors.[1]
As you move down a period, the outer electrons become more easily accessed, as the outer electrons are increasingly screened from the nuclear charge by the inner electrons.[2] This is why both ionization energy and electron affinity decreases down a period.
Classical organometallic chemistry uses metal carbonyl stretching frequencies as a direct measure of π back-bonding and electron density.[3] For a recent discussion, see: Chem. Sci. 2016, 7, 1174. Compare the stretching frequency of the group VI metal hexacarbonyls [4]: $\ce{Cr(CO)6}$: $\pu{2000 cm^-1}$ and $\ce{W(CO)6}$: $\pu{1987 cm^-1}$. Tungsten donates more electron density back into the carbonyl than does $\ce{Cr}$.
The importance of relativistic effects in structure calculations is frequently the subject of reviews.[5]
References:
- Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, Ch. 6
Waldron, K. A.; Fehringer, E. M.; Streeb, A. E.; Trosky, J. E.; Pearson, J. J. Screening Percentages Based on Slater Effective Nuclear Charge as a Versatile Tool for Teaching Periodic Trends. J. Chem. Educ. 2001, 78 (5), 635. DOI: 10.1021/ed078p635.
Tolman, C. A. Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis. Chem. Rev. 1977, 77 (3), 313–348. DOI: 10.1021/cr60307a002.
Clark, R.; Crociani, B. Solvent effects on the infrared spectra of chromium, Molybdenum and tungsten hexacarbonyls. Inorganica Chimica Acta 1967, *1undefined 12–16. DOI: 10.1016/S0020-1693(00)93131-1.
Pyykko, P. Relativistic effects in structural chemistry. Chem. Rev. 1988, 88 (3), 563–594. DOI: 10.1021/cr00085a006.