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I came across cyanide and isocyanide in an example for functional isomerism. As they are also ambident nuclephiles, I wanted to know if other ambident nucleophiles would also exhibit functional isomerism.

Thanks

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Yes, ambident nucleophiles show functional isomerism. Two examples are:

  1. Cyanide ($\ce{CN}$) and isocyanide ($\ce{NC}$)
  2. Nitrite ($\ce{ONO}$) and Nitro ($\ce{NO2}$)
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    $\begingroup$ Nitpick: Cyanide is already mentioned in OP's question. Here is a different example: "thiocyanate $\ce{-SCN}$". $\endgroup$ – Nilay Ghosh Jun 21 at 8:45

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