I was reading the Wikipedia article about Sucrose, when I noticed that the skeletal formula was missing some $\ce{C}$ and $\ce{H}$ atoms. The chemical formula being $\ce{C12H22O11}$, I counted the $11$ Oxygen parts. But there seem to be only $3$ $\ce{C}$ atoms and $14\, \ce{H}$ atoms, if I counted correctly. My chemistry lessons date back about $15$ years, so I'd like to understand where the missing carbon and oxygen is hidden within the skeletal formula.
1 Answer
Since your chemistry lessons date back about 15 years, I'd loke to refreash your organic chemistry knowledge. You may need to be aware that carbon can make maximum if 4 single bonds. Therefore, when you have a line structure of organic compound like sucrose (see below), keep in mind that an each corner represent a carbon atom and appropriate hydrogen atoms, which are not shown. For example, if a corner contains only three bonds (as shown in most of sucrose molecule), then the forth bond is $\ce{C-H}$ bond:
I have put those $\ce{C-H}$ at each corner, which are representing them. However, the anomeric corner of fructose molecule already has 4 bonds. Therefore, that corner represents only $\ce{C}$ as indicated in turquoise color. Therefore, the molecular formula of sucrose can be counted as $\ce{C12H22O11}$.
CH
ions then? That would account for the missing Hydrogen. $\endgroup$