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What happens to the solute if you heat up a supersaturated solution? Since a supersaturated solution is already more than saturated with solute and unstable, my theory is that as you heat the supersaturated solution, the solubility limit will have been increased enough to allow all of the solute to dissolve. So technically, the solute does not precipitate out if you heat it enough.

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  • $\begingroup$ Is the solvent volatile? It depends on how you set up the experiment. If more solvent evaporates then the concentration of the solute will increase. $\endgroup$
    – Buck Thorn
    Jul 31, 2020 at 9:58
  • $\begingroup$ Molten sugar is miscible with water. NaCl in water at 100°C not. NaCl in water at 800°C (under high pressure) possibly, you´ll have to check. $\endgroup$
    – Karl
    Aug 1, 2020 at 5:57

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Two caveats:

  1. If you sufficiently disturb a supersaturated solution, the solute will spontaneously come out solution. So you would need to heat it without sufficiently disturbing it.

  2. The solubilities of some solutes decrease with temperature. So let's assume your solute's solubility increases with temperature (as is the case for most, but not all, solids dissolved in a liquid).

So if we allow for the above then, as you heat the solution, you will eventually reach at point at which it is no longer supersaturated.

Indeed, the reverse of this is how supersaturated solutions are typically prepared: A solution is prepared at a high temperature with a concentration of dissolved solid just below the saturation point (you don't want any undissolved solid left, since that will act as a nucleation site and thus prevent supersaturation). Then it is carefully cooled. So, by heating it sufficiently, you would simply be moving it back towards the starting point.

Finally, someone might argue that, if the solution is supersaturated near the boiling point, it might not be possible to heat it up sufficiently to get below the saturation concentration. I suppose that's possible in theory, but I don't know how you would prepare such a system, since it couldn't be created using the typical cooling process.

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  • $\begingroup$ The solubility of all solutes decrease with temperature. $\endgroup$
    – Jon Custer
    Jul 31, 2020 at 14:19
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    $\begingroup$ @JonCuster The OP is talking about the solute preciptating out, so clearly he or she is referring to a solid dissolved in a liquid. If the solvent is water, solubilities of solids typically (but don't always) increase with temperature. And even if the solute were a gas, it's not generally the case that the solubilities of gases decrease with temperature. In water they generally do, but in organic solvents one can see the opposite. $\endgroup$
    – theorist
    Aug 1, 2020 at 4:24

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