At the time when Rutherford's gold foil experiment was performed, Thomson's plum pudding model was believed to be true (at least by Rutherford himself and his students).
With this model in mind Rutherford predicted that most of the alpha particles will be deflected by at most a fraction of a degree (sourced by this Wikipedia page), but why?
In my opinion, since according to the plum pudding model the mass of an atom was assumed to be uniformly distributed and the atomic mass of gold is nearly 50 times larger than the mass of an alpha particle, and gold is solid, therefore much less intermolecular space will be present, so, most of the alpha particles should rebound or get deflected by a large angle.