The basicity order of aniline and 2,6-tertiary butyl aniline is the latter greater than the former. Why does the ortho effect not make it the other way around? Or am I missing something?
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1$\begingroup$ Is your first sentence a statement or a question? Providing pKb's would be helpful. $\endgroup$ – user55119 Jan 23 '20 at 16:51
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1$\begingroup$ Here u have to consider SIP effect .... $\endgroup$ – Muskaan Jan 23 '20 at 16:54
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1$\begingroup$ Ortho effect is present in anilines too $\endgroup$ – Atharva Jan 23 '20 at 17:09
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1$\begingroup$ chemistry.stackexchange.com/questions/15412/… chemistry.stackexchange.com/questions/7683/… $\endgroup$ – Mithoron Jan 23 '20 at 18:16
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1$\begingroup$ chemistry.stackexchange.com/questions/14767/… chemistry.stackexchange.com/questions/87461/… $\endgroup$ – Mithoron Jan 23 '20 at 18:23
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