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I'm sorry if this is a broad question, but I am trying to plan a simple experiment. I am wondering is there a somewhat simple way of continuously measuring $\ce{CO2}$. I already know the initial carbon dioxide content is around $\pu{2.2g}$ from research, but I don't know how this result is reached.

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  • $\begingroup$ Monitor pH continuously and stop when you hit the pH that corresponds to atmospheric $P_\ce{CO2}$ equilibrium in solution. $\endgroup$ – Todd Minehardt Dec 17 '19 at 21:50
  • $\begingroup$ You want to know how the initial CO2 content of 2.2 grams is determined or do you want to plan an experiment to monitor the loss of CO2 from Coca Cola over time? $\endgroup$ – J. Ari Dec 17 '19 at 23:03
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    $\begingroup$ @ToddMinehardt, there is citric acid and phosphoric acid too. Not sure if the pH will change significantly. $\endgroup$ – M. Farooq Dec 18 '19 at 1:25
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    $\begingroup$ @M.Farooq - True, good point. That Coke might go well with a Twinkie, reported to have a shelf life of 25 days... $\endgroup$ – Todd Minehardt Dec 18 '19 at 1:56
  • $\begingroup$ With some control measurements (tap water, carbonated water and flat soda) and calibration curves, IR spectroscopy might provide a contactless and direct quantification of CO2 content. $\endgroup$ – Nicolau Saker Neto Dec 18 '19 at 11:59
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Measure the change in mass over time of the remaining liquid. Though some water will also evaporate, you can control for that by keeping the humidity near 100%.

If you have to be precise, collect the outgassed $\ce{CO2}$ in a liquid-nitrogen cold trap. Check the mass of the condensate, which should equal that lost from the soda. Check purity, to be really finicky.

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    $\begingroup$ You can also get flat Coke to compare, to get an approximation of how much mass loss is due to water evaporation (although the evaporation rate of water from flat soda may not be exactly the same as from carbonated). $\endgroup$ – Acccumulation Dec 20 '19 at 5:29
  • $\begingroup$ @Acccumulation, the question asks for a , "way of continuously measuring CO2." The flat soda only gives an end-point... and what determines flat? One hour? One day? One week? $\endgroup$ – DrMoishe Pippik Dec 20 '19 at 18:50
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Measure concentration in a fixed volume of air

Easiest way might be to put it in a sealed impermeable bag or box and measure the CO2 concentration over time. Home hobbyists use something like the MG-811 CO2 sensor or a simple non-dispersive optical sensor and connect it to a Raspberry Pi or Arduino using an analog to digital converter chip (ADC). For (a little) more on that see this answer to Why are CO2 sensors so expensive when CO sensors aren't?

...CO2 sensors are either solid electrolyte chemical cells like the MG-811 or newer versions (see this question) or they are Non-dispersive Infrared Light sensors (NDIRs) based on optical absorption of a certain wavelength of infrared light, using a hot filament or other light source to produce IR and a narrow multilayer optical filter to select one of the strong absorption lines of CO2. The more CO2, the more the reduction in the transmission of light in the optical path of the sensor.

You would estimate the total volume of trapped air and multiply by the fraction that is CO2 (at each time point) to get the accumulated amount of CO2 released by the liquid.

Measure amount collected in a CO2 scrubber

Building on @DrMoishe Pippi's proposed technique though I can't guarantee precision, you could try to use something else to absorb CO2 besides a cold trap.

I propose that you consider a carbon dioxide scrubber.

However, lithium hydroxide may not be suitable for home use as it is very dangerous to touch or otherwise contact! So you should do this with supervision.

From PubChem; Lithium hydroxide (Compound)

Lithium hydroxide, solution appears as a clear to water-white liquid which may have a pungent odor. Contact may cause severe irritation to skin, eyes, and mucous membranes. It may be toxic by ingestion, inhalation and skin absorption. It is used to make other chemicals.


Regenerative carbon dioxide removal system

The regenerative carbon dioxide removal system (RCRS) on the space shuttle orbiter used a two-bed system that provided continuous removal of carbon dioxide without expendable products. Regenerable systems allowed a shuttle mission a longer stay in space without having to replenish its sorbent canisters. Older lithium hydroxide (LiOH)-based systems, which are non-regenerable, were replaced by regenerable metal-oxide-based systems. A system based on metal oxide primarily consisted of a metal oxide sorbent canister and a regenerator assembly. It worked by removing carbon dioxide using a sorbent material and then regenerating the sorbent material. The metal-oxide sorbent canister was regenerated by pumping air at approximately 400 °F (204 °C) through it at a standard flow rate of 7.5 cu ft/min (0.0035 m3/s) for 10 hours.

Exactly how to do it will require some input by an actual chemist. That might be best asked as a new question "How to use off-the-shelf LiOH (pellets or powder) as a home-made CO2 scrubber?" for example.

If you put the open container in a larger container (sealed, impermeable plastic bag or box) with something else that absorbed CO2 and held on to it at room temperature, you could weigh it before and after as a lower limit at least to the CO2 lost by the liquid.

If you have ever seen the movie Apollo 13 or know the story of the CO2 scrubber canister (1, 2) you might recollect that it removed the astronaut's exhaled CO2 from the cabin air and held it within the solid LiOH pellets it contained.

Because they needed it to be compact but to scrub a large volume of air, the spacecraft used a fan to circulate air through the scrubber. But in your case it might be possible to use lithium hydroxide or another material like silver oxide (see this answer and EMU METOX Performance Testing).

Here is some data from that report. You can see that the ~14 kg of silver oxide could hold roughly 0.8 kg of CO2.

enter image description here

History, from NASA's Building an Apollo 13 LiOH Canister Adapter:

enter image description here

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    $\begingroup$ Pretty much any strong base can be used to scrub $\ce{CO2}$ from the air. Sodium hydroxide, for example, is commonly available in general stores. While it's also caustic (like any strong base) and needs to be handled with care, the precautions needed are merely the general ones for safe handling of laboratory chemicals: basically keep it out of your eyes and mouth, don't inhale the fumes if you heat it, try not to get any on your skin and if you do, rinse it off promptly. $\endgroup$ – Ilmari Karonen Dec 18 '19 at 9:07
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For a direct measurement of $\ce{CO2}$ content, it is possible to use infrared (IR) spectroscopy. Infrared radiation can be absorbed by molecules, causing them to vibrate. The exact frequency of the radiation absorbed is often characteristic of certain bonds or functional groups.

In particular, the fundamental antisymmetric stretching mode of $\ce{CO2}$ in aqueous solution (specifically the carbon-12 isotopologue $\ce{^{12}CO2(aq)}$, not carbonic acid $\ce{H2CO3}$) is excited by photons of wavelength $\mathrm{4268\ nm}$ (more commonly reported as $\mathrm{2342.9\ cm^{-1}}$ wavenumbers for historical reasons). This vibrational mode is useful for the following reasons:

  • The absorption peak is quite sharp, with a "width" (FWHM) of only $\mathrm{9\ cm^{-1}}$
  • The molar absorptivity is strong, at $\mathrm{1.5 \times 10^6\ cm^2\ mol^{-1}}$
  • The absorption intensity varies linearly with concentration
  • Few other substances have strong absorption in the same region

Altogether, these properties make the peak suitable for analytic measurements. This has been discussed in Vib. Spect., 1992, 4 (1), 105-108. Though the article did not explore the possibility, it's likely the technique could be adapted for use in sodas. Measurements could potentially be performed directly in unopened bottles. Furthermore, similar benefits exist for measuring gaseous $\ce{CO2}$, so an independent measurement of the space above the liquid could be performed with the same instrument, and the results cross-checked for additional accuracy.

This wouldn't be very easy for a hobbyist doing kitchen chemistry (though handheld/compact/portable IR spectrometers exist and aren't tremendously expensive), but such a study would be very well within reach of most chemical laboratories.

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You might want to use a $\ce{CO2}$ ion selective electrode, such as PS-3517 from PASCO:

This Carbon Dioxide Ion Selective Electrode (ISE) Probe is a gas-sensing electrode that allows fast, simple, eco-nomical, and accurate measurement of dissolved CO2 in aqueous solutions

The advantage over other methods is that you measure the concentration in situ and therefore do not have to concern yourself with how to capture $\ce{CO2}$ quantitatively (weighting small amounts), how to discriminate $\ce{CO2}$ from other gases (for instance water, which must be removed from the gas or prevented from condensing in the $\ce{CO2}$ trap), on complicated intermittent sampling, and on how the rate of capture might affect your measurement.

It should work with Coca-Cola:

pH Range: Samples and standards must be adjusted to below pH 4.00

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  • $\begingroup$ +1 This could potentially (pun intended) be the best overall solution for the OP, but what's the minimum equipment necessary to read the probe? Can it be done with a variety of meters or electrometers that could be borrowed (something with very high impedance that reads millivolts), or would this require a purchase specifically of a "PASCO box" of some kind? Would a calibration solution also be needed as well or does this kind of probe yield at least approximate results without using a standard solution? $\endgroup$ – uhoh Dec 19 '19 at 2:33
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    $\begingroup$ @uhoh If I understood correctly the probe can be operated connected to a standard pH meter, see eg an instruction manual here: d2n0lz049icia2.cloudfront.net/product_document/… You do need to calibrate it, this requires appropriate calibration solutions which can be purchased separately. $\endgroup$ – Buck Thorn Dec 19 '19 at 9:23
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    $\begingroup$ Actually, a CO2 standard solution is included with the probe. The meter would be calibrated with regular pH calibration solutions. $\endgroup$ – Buck Thorn Dec 19 '19 at 9:25
  • $\begingroup$ okay sounds great, thanks! $\endgroup$ – uhoh Dec 19 '19 at 15:13
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A very different method which should work well given the high initial level of carbonation in Coca-Cola (141 mM by my estimation based on this post) is $\ce{^{13}C}$-NMR. See for instance Reference 1. Spectra of liquid solutions are high in resolution and one dimensional data can be acquired continuously in a span of a few minutes per spectrum.

Note the spectra might be acquired at natural $\ce{^{13}C}$ abundance (about 1%) or spiked (enriched) with $\ce{^{13}C}$, which of course will be (a lot) more expensive. You might on the other hand be able to capture for reuse the released $\ce{^{13}C}$ with one of the methods suggested in one of the other answers.

References

  1. Qi Yang,Mark Bown, Abdelselam Ali, Dave Winkler, Graeme Puxty and Moetaz Attalla. A Carbon-13 NMR Study of Carbon Dioxide Absorption and Desorption with Aqueous Amine Solutions. Energy Procedia 1 (2009) 955–962
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