In the reaction $\ce{N2 (g) + O2(g) -> 2NO (g)}$ my textbook[1] says $q_v$ and $q_p$ are not the same, without any explanation.
I know that \begin{align} \Delta U &= q_p + w\\ \Delta U &= q_p - P\Delta V\\ \Delta U &= q_p - Δn_\mathrm{gases}RT \end{align}
I also know that $$\Delta U = q_v.$$
because under constant volume, work done ($-P\Delta V$) is zero, since there's no change in volume.
In the reaction mentioned,
$$n_\mathrm{gases} = 0,$$
so shouldn't
$$\Delta U = q_p$$
and therefore
$$q_p = q_v?$$
Here's a picture of question 143 in Chapter 7 of [1]. The answers say a) and d) are false:
- Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette: General Chemistry: Principles and Modern Applications, 11th edition. Published by Pearson (February 23rd 2016)