Can I apply group theory to the $\sigma$ orbitals of benzene? I have already seen it be applied to the $\pi$ orbitals, but I can't find an application to the $\sigma$ in literature. In this case, could I find the characters of the representation with which the $\sigma$ orbitals are transformed and decompose it in the irreducible representatios of the point group of benzene (that is the $D_{6h}$)?

  • $\begingroup$ You can, but it is not much fun. $\endgroup$ – Ivan Neretin Jun 5 '19 at 5:24

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