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Consider a solution of $\text{HCl}$ with a concentration of $10^{-10}$ $\text{M}$. Now, if I find it's pH: $$\text{pH} = -\log([\text{H}^+])$$ $$\text{pH} = -\log(10^{-10}) = 10$$ At room temperature, $\text{pH} + \text{pOH} = 14 \implies \text{pOH}$ of the given acid is $4$. This means that the $[\text{OH}^-]$ ions is $10^{-4}$ $\text{M}$. But from where do these $\text{OH}^-$ ions come?

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marked as duplicate by M.A.R., Community May 31 at 8:49

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    $\begingroup$ At this dilution rates you can no longer get away with using concentration instead of activity, and you have to calculate $\mathrm{pH}$ as $\mathrm{pH} = -\log a(\ce{H+}).$ Note that $\mathrm{pH}$ also heavily relies on solvent/medium. $\endgroup$ – andselisk May 31 at 7:54
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    $\begingroup$ I object. At dilutions this great, you can more than ever rely on using concentration instead of activity. Now to the point. What is the pH of pure water? $\endgroup$ – Ivan Neretin May 31 at 8:24
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    $\begingroup$ @andselisk right answer, but to another question ;-) $\endgroup$ – Karl May 31 at 8:24
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    $\begingroup$ In one word: Autoprotolyis $\endgroup$ – Karl May 31 at 8:26
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    $\begingroup$ ^ That said, I think this is a useful duplicate for search, concisely worded. $\endgroup$ – M.A.R. May 31 at 8:42

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