How should I compare the order of rate of 1.formaldehyde 2.ethanal 3.p-nitrobenzaldehyde 4.p-methoxybenzaldehyde
For nucleophilic addition the rate depends on the intensity of electron deficiency of carbonyl carbon. It also depends inversely on the steric hindrance
I know that the rate of p-nitrobenzaldehyde will be higher than that of para-methoxybenzaldehyde due to electron withdrawal of nitro group and electron donation of methoxy group Similarly formaldehyde will have higher rate than ethanal due to the hyperconjugative effect of methyl group which decreases the electron deficiency.
What I want to know is how to compare between the aliphatic and the aromatic ones Plus I want to know when all I should give more importance to steric effect than the electron deficiency and vice versa.