Sulfuryl Chloride and Sulfuryl Fluoride have π-bonds between S and O atoms. I have read that SO2Cl2 has one pπ-dπ and one pπ-pπ bond, but can't verify it anywhere on the net.

Is the above statement a fact? If yes, is the same phenomenon observable in SO2F2? Please include reasons too, if possible.

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    $\begingroup$ There's little or no involvement of d-orbitals in bonding. $\endgroup$ – orthocresol Dec 24 '18 at 14:35
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    $\begingroup$ No it's not a fact and there's no π-bond there. There are only drawn like that sometimes. $\endgroup$ – Mithoron Dec 24 '18 at 22:00
  • $\begingroup$ chemistry.stackexchange.com/questions/39396/… $\endgroup$ – Mithoron Dec 24 '18 at 22:03
  • $\begingroup$ I can swear upon it that I've seen innumerable textbooks show π bonds. Had no idea that d-orbitals' involvement was non-existent. Should I withdraw the question? $\endgroup$ – William R. Ebenezer Dec 26 '18 at 13:19
  • $\begingroup$ Could you provide links to any publication that reports this, if possible? $\endgroup$ – William R. Ebenezer Dec 26 '18 at 13:21

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