# Does the hydrohelium dication exist?

It is well-known that there exists the $$\ce{He2^2+}$$ dication, and also $$\ce{HHe+}$$ and $$\ce{H2+}$$ cations. But I could not find any definite information about the existence or inexistence of the $$\ce{HHe^2+}$$ cation.

It would be isoelectronic to $$\ce{H2+}$$, but would have a weaker bonding due to greater helium nucleus charge. It looks unlikely to be stable, but did anyone prove it by calculation or experiment?

• There is a paper by S. K. Knudson, Semiclassical energies of low-lying states of one-electron diatomics. By skipping through the paper I found some calculations on your compound. But I didn't have time to read through yet. So perhaps it's not helpful at all to you. – Justanotherchemist Dec 18 '18 at 12:32
• Just in case you want to look at the paper though: doi.org/10.1016/S0301-0104(00)00006-9 In my first skim I found the following quote (tl;dr): 'The only bound ground state is that for $\ce{H2+}$; the other cations have repulsive ground states. ' – Martin - マーチン Dec 18 '18 at 16:57
• @Martin-マーチン, however they might have stable excited states. Surely there must be at least one. This is also the case for the He2 dimer. – user1271772 Dec 18 '18 at 19:22

I am not sure how to elaborate much beyond saying that yes, there are bound states of $$\ce{HHe^{2+}}$$. I cite three papers below which give numerical calculations of various states, ref. 1 gives calculations for the lowest 20 states of the system.
It appears to be that the 1s$$\sigma$$ is not a bound state in this system, but the 2p$$\sigma$$ state is bound. I would expect there are some other bound states as well.