Cyclopentadienylmolybdenum tricarbonyl, $\ce{MoC8H5O3}$, dimerizes to form the cyclopentadienylmolybednum tricarbonyl dimer, $\ce{(MoC8H5O3)2}$.
How was it discovered that it does this?
If you had an sample of a pure substance, but didn't know if it had dimerized or polymerized, what information would you need to find out if it had?