# Why does formic acid give positive Fehling's test?

$$\ce{HCOOH ->[\text{Fehling's solution}] CO2 + H2O}$$

The points discussed in a previous question do not account for the fact that formic acid also gives positive Fehling's test since it is not enolisable. Then what is the reason/mechanism for the reaction?

• I thought that the exact mechanism is not known in case of both fehlings and tollens. – user57048 Aug 23 '18 at 6:15
• Formic acid is something like an aldehyde, it has a hydrogen atom attached to a carbonyl group. – Oscar Lanzi Aug 23 '18 at 9:47
• Because Fehling's solution oxidizes enolizable aldehydes to carboxylic acids, it does not preclude all other oxidations. Draw cupric formate and move formate electrons toward copper. – user55119 Aug 23 '18 at 23:17

According to some people:

If you look carefully, you will find both the aldehyde radical and the carboxyl radical in formic acid:

The red line shows the aldehyde functional group character and the blue line indicates the carboxyl functional group character.

As a result, it has mainly characteristics of carboxyl compound, but sometimes shows carbonyl character as well which happens in case of tollen's reagent and fehling's solution reacting with it.

You can identify it by doing the 2:4-DNPH test to which the formic acid doesn't respond.

But to me and most other people:

This reaction certainly is given by aldehydes, it is not specific for this class of compound since many other acids, such as tartaric or citric, similarly reduce silver nitrate. The reduction of mercuric chloride to mercurous chloride by formates likewise offers no support for the aldehyde theory, since aldehydes in general, including formaldehyde, cannot effect this change. Actually, formates give none of the reactions which characterize an aldehyde; thus they fail to restore the colour to Schiff's reagent, produce no reaction with 2.4 dinitrophenylhydrazine hydrochloride, and above all do not reduce Fehling's solution, which is probably the most specific of all aldehyde reagents.

• They’re not radicals; at best, they are functional groups. But formic acid really doesn’t undergo any typical aldehyde reactions, so calling the carbonyl group an aldehyde is missing the point … – Jan Nov 1 '19 at 11:32
• edited; I at first didn't notice that i didn't include the whole answer. Sorry for that – sakib Nov 1 '19 at 14:39