2
$\begingroup$

For example, adding $\ce{HCl}$ to the very insoluble $\ce{CaF2}$ will help it further dissolve. How?

I believe the concept deals with equilibrium and Le Chatelier's Principle:

$$ \ce{ CaF2 <=> Ca^2+ + 2F^-} $$

Does adding $\ce{H+}$ react with the $\ce{F-}$, which shifts the equilibrium to the right-hand side and therefore further dissolve the salt?

$\endgroup$

1 Answer 1

4
$\begingroup$

In general, the solubility of a sparingly soluble salt having a basic anion will increase with the addition of a strong acid. Given:

$$\ce{X+A- <--> X+ + A-}$$

where $K_{sp}$ is small and A- is a weak base, the addition of a strong acid will form HA, driving the reaction to the right and increasing $K_{sp}$.

In the specific case of

$$\ce{CaF2 <--> Ca^2+ + 2F−}$$

the addition of $\ce{HCl}$ gives

$$\ce{CaF2 + 2HCl <--> Ca^2+ + 2Cl- +2HF}$$

driving the reaction to the right, thus increasing the solubility of $\ce{CaF2}$. Note that $\ce{HF}$ itself is a weak acid, having a pKa of $3.17$, and will be in equilibrium with $\ce{H+}$ and $\ce{F-}$.

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.