0
$\begingroup$

This was a question on a review sheet for Lewis structures.

Now I could draw $\ce{SO4^2-}$ with no issues, but I can't make sense out of $\ce{SO4^2+}$ because I can't even make bonds to all $\ce{O}$ without exceeding the number of bonding electrons.

This is on a high school AP review so it is possible that there are exceptions to the normal rules, but I can't see how any of them apply. I could just chop electrons off the oxygens and leave it depleted, but I don't imagine that is a stable form of a cation which would exist?

A quick check doesn't turn up anything so is this a real thing or was it just a typo?

$\endgroup$
1
  • 11
    $\begingroup$ Looks like a typo. $\endgroup$
    – aventurin
    Commented Jan 2, 2017 at 23:06

1 Answer 1

1
$\begingroup$

How about $\ce{O=O+-S+=O+-O-}$ ? I don't know if it exists but it is a closed shell species and has a delocalized pi bonded structure that might give it some stability.

$\endgroup$
1
  • 1
    $\begingroup$ A better resonance structure of your suggestion would be $\ce{O=\overset{+}{O}-S-\overset{+}{O}=O}$ which has less formal charges, is more symmetric and is still conjugated. $\endgroup$
    – Jan
    Commented Jan 3, 2017 at 22:33

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.