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For a complex alkyl substituent, (at least the ones I have come into contact with thus far) you name it as a chain numbering from the first non-parent carbon and placing the name in square brackets: e.g. isopentyl can also be named [3-methylbutyl]. What is the convention for more complex benzene-based substituents? Specifically, can you still use the more common names like phenol and toluene as a parent for your name if say you bond C5 of 2,3-dimethylphenol to your parent and what suffix will you use?

For a complex alkyl substituent, you name it as chain numbering from the first non-parent carbon and placing the name in square brackets. What is the convention for more complex benzene-based substituents? Specifically, can you still use the more common names like phenol and toluene as a parent for your name if say you bond C5 of 2,3-dimethylphenol to your parent and what suffix will you use?

For a complex alkyl substituent, (at least the ones I have come into contact with thus far) you name it as a chain numbering from the first non-parent carbon and placing the name in square brackets: e.g. isopentyl can also be named [3-methylbutyl]. What is the convention for more complex benzene-based substituents? Specifically, can you still use the more common names like phenol and toluene as a parent for your name if say you bond C5 of 2,3-dimethylphenol to your parent and what suffix will you use?

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Nomenclature of complex benzene-based substituents

For a complex alkyl substituent, you name it as chain numbering from the first non-parent carbon and placing the name in square brackets. What is the convention for more complex benzene-based substituents? Specifically, can you still use the more common names like phenol and toluene as a parent for your name if say you bond C5 of 2,3-dimethylphenol to your parent and what suffix will you use?