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Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: $-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density $(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

PerfluorohexanePerfluorohexane is just over the boiling point limit at $56\ \mathrm{^\circ C}$, but it has a molar mass of $338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoridetungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl-37}$, with a molar mass of $460\ \mathrm{g/mol}$, which makes it over 50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of $75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: $-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density $(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at $56\ \mathrm{^\circ C}$, but it has a molar mass of $338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl-37}$, with a molar mass of $460\ \mathrm{g/mol}$, which makes it over 50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of $75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: $-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density $(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at $56\ \mathrm{^\circ C}$, but it has a molar mass of $338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl-37}$, with a molar mass of $460\ \mathrm{g/mol}$, which makes it over 50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of $75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

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Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: $-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density $(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at $56\ \mathrm{^\circ C}$, but it has a molar mass of $338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

Osmium octafluoride is slightly denser than perfluorohexane and $\ce{WF6}$, but it is even more corrosive than $\ce{WF6}$ and its boiling point is $47\ \mathrm{^\circ C}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl-37}$, with a molar mass of $460\ \mathrm{g/mol}$, which makes it over 50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of $75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: $-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density $(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at $56\ \mathrm{^\circ C}$, but it has a molar mass of $338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

Osmium octafluoride is slightly denser than perfluorohexane and $\ce{WF6}$, but it is even more corrosive than $\ce{WF6}$ and its boiling point is $47\ \mathrm{^\circ C}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl-37}$, with a molar mass of $460\ \mathrm{g/mol}$, which makes it over 50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of $75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: $-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density $(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at $56\ \mathrm{^\circ C}$, but it has a molar mass of $338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl-37}$, with a molar mass of $460\ \mathrm{g/mol}$, which makes it over 50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of $75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

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user7951

Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: -1.7ºC$-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density (~13kg/m^3)$(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is 28C $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at 56ºC$56\ \mathrm{^\circ C}$, but it has a molar mass of 338$338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

Osmium octafluoride is slightly denser than perfluorohexane and $\ce{WF6}$, but it is even more corrosive than $\ce{WF6}$ and its boiling point is 47ºC$47\ \mathrm{^\circ C}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl}$-37$\ce{Cl-37}$, with a molar mass of 460$460\ \mathrm{g/mol}$, which makes it over 50%50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of 75ºC$75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: -1.7ºC.

Perfluoropentane is similar and rarer but somewhat higher density (~13kg/m^3) in proportion to its higher molecular mass. Its boiling point is 28C (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at 56ºC, but it has a molar mass of 338 which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

Osmium octafluoride is slightly denser than perfluorohexane and $\ce{WF6}$, but it is even more corrosive than $\ce{WF6}$ and its boiling point is 47ºC.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl}$-37, with a molar mass of 460, which makes it over 50% denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of 75ºC, decomposes on contact with air, is toxic and slightly radioactive.

Perfluorobutane is inert and has almost twice the density of sulfur hexafluoride. It is non-toxic enough that it is used in fire extinguishers and injected as a contrast agent for ultrasound. Boiling point: $-1.7\ \mathrm{^\circ C}$.

Perfluoropentane is similar and rarer but somewhat higher density $(\sim13\ \mathrm{kg/m^3})$ in proportion to its higher molecular mass. Its boiling point is $28\ \mathrm{^\circ C}$ (uncomfortably warm, but your thermostat can go that high). This is the densest gas that strictly meets all the criteria in the OP.

If we relax the criteria a bit:

Perfluorohexane is just over the boiling point limit at $56\ \mathrm{^\circ C}$, but it has a molar mass of $338\ \mathrm{g/mol}$ which makes it slightly denser in gas form than tungsten hexafluoride ($\ce{WF6}$). It's also inert and non-toxic, unlike $\ce{WF6}$.

Osmium octafluoride is slightly denser than perfluorohexane and $\ce{WF6}$, but it is even more corrosive than $\ce{WF6}$ and its boiling point is $47\ \mathrm{^\circ C}$.

The ultimate gas density would be uranium hexachloride using depleted uranium and $\ce{Cl-37}$, with a molar mass of $460\ \mathrm{g/mol}$, which makes it over 50 % denser in gas form than tungsten hexafluoride, and 3 times denser than sulfur hexafluoride, but it has a boiling point of $75\ \mathrm{^\circ C}$, decomposes on contact with air, is toxic and slightly radioactive.

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