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Apr 13, 2017 at 12:57 history edited CommunityBot
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Jul 15, 2016 at 8:28 history edited bon CC BY-SA 3.0
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Jul 14, 2016 at 19:50 comment added permeakra @bon Apologies. This work dx.doi.org/10.1071/CH04113 suggests that there is some pi-interaction involved and it has to do with d-orbitals.
Jul 14, 2016 at 19:26 comment added bon @permeakra No it says that they mostly participate in sigma bonding. Read the section on the fourth page about $d_{\sigma}$ and $d_{\pi}$ contributions. pubs.acs.org/doi/pdf/10.1021/ja00273a006
Jul 14, 2016 at 18:24 comment added permeakra @bon But the article points that sulphur d-orbitals are mostly participating in pi-bonding !
Jul 14, 2016 at 9:21 history edited bon CC BY-SA 3.0
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Jul 14, 2016 at 9:11 comment added bon @StevenStewart-Gallus More or less. I read the paper provided by DavePhD and added some more detail in my answer. What do you mean by 'does it have empty spots in it'?
Jul 13, 2016 at 20:52 comment added Ms. Molly Stewart-Gallus So, the sulfur atom is more like a +3 ion and has a valence electron configuration like: $[\ce{Ne}] \underset{(3s)^{0.97}(3p)^{1.82}(3d)^{0.24}}{[\uparrow \vert \uparrow \vert \uparrow ]}$? Is this set of hybridized orbitals completely symmetrical or does it have empty spots in it?
Jul 13, 2016 at 19:57 history answered bon CC BY-SA 3.0