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Jan 27, 2015 at 11:44 comment added cbeleites That "looses strength with exposure to air" is carbonate forming from $\ce{CO_2}$ captured from the ambient air. Which means that you have a small amount of buffer in the solution. pKA $\ce{HCO_3^2-}$ is 10.3, so this may be the explanation for the bump in the second titration curve.
Aug 9, 2013 at 13:09 vote accept Tim Vermeulen
Aug 17, 2015 at 13:51
Jun 9, 2013 at 1:03 history answered user467 CC BY-SA 3.0