Timeline for What is correct sign convention for Helmholtz free energy change?
Current License: CC BY-SA 4.0
7 events
when toggle format | what | by | license | comment | |
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Oct 21, 2023 at 18:02 | history | edited | Proscionexium | CC BY-SA 4.0 |
deleted 18 characters in body
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Aug 22, 2023 at 2:46 | comment | added | jimchmst | It is not a matter of preference. It is a matter of defining the internal energy of a system. Either add the work done on the system or subtract the work done by the system. The work must result in random change in molecular momentum and change the heat content of the system. | |
Aug 19, 2023 at 4:12 | vote | accept | Proscionexium | ||
Aug 19, 2023 at 3:59 | answer | added | Poutnik | timeline score: 4 | |
Aug 18, 2023 at 5:16 | comment | added | Proscionexium | So can I say (4) and (6) are fundamentally same in meaning? And sign is a matter of preference? | |
Aug 18, 2023 at 5:09 | comment | added | Poutnik | Is not it obvious ? If W is work done to system then W= +ΔA. If by the system then W=-ΔA. It is not about intuition but about historical context. Work done by the system was used by engineers/physicists, more interested what the system can do. Chemists/scientists were interested more in what happens to the system. | |
Aug 18, 2023 at 5:02 | history | asked | Proscionexium | CC BY-SA 4.0 |