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The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex andand it should break. Besides, the medium is acidic so it should catalyse this process.

OnIn generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why the lacollactol is favoured more in this case?

question

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

On generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why the lacol is favoured more in this case?

question

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

In generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why lactol is favoured more in this case?

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Satya
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enter image description herequestion

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

On generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why the lacol is favoured more in this case?

enter image description here

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

On generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why the lacol is favoured more in this case?

question

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

On generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why the lacol is favoured more in this case?

Added further developments to my attempt
Source Link
Satya
  • 454
  • 4
  • 11

enter image description here

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

On generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why the lacol is favoured more in this case?

enter image description here

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

On generalising, my question is are lactols stable?

enter image description here

The answer given is (D) but I think (B) should be the answer as the concerned benzylic carbon in option (D) is an unstable tetrahedral complex and it should break. Besides, the medium is acidic so it should catalyse this process.

On generalising, my question is: are lactols stable?

Edit: I found online that there is an equilibrium between lactols and corresponding hydroxyaldehyde. So, why the lacol is favoured more in this case?

Source Link
Satya
  • 454
  • 4
  • 11
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