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It was first discovered by Cady that when fluorine is bubbled through 3 N$\pu{3 N}$ nitric acid, then a remarkable compound, fluorine nitrate ($\ce{FNO3}$) is formed. It boils at -42 ℃$\pu{-42 ^\circ C}$ and is a very strong oxidizing agent and is capable of liberating iodine from iodides and in gaseous states, it explodes around 200-300 ℃$\pu{200-300 ^\circ C}$.

References

  1. The reaction of Fluorine with Nitric acid and with solid Potassium Nitrate to form NO3F by Don M. Yost and Alan Beerbower, J. Am. Chem. Soc. April 1935, 57(4) 782. DOI: https://doi.org/10.1021/ja01307a520

  2. Prof. Dr. Otto Ruff, Dr. Walter Kwasnikie, Die Fluorierung der Salpetersäure. Das Nitroxyfluorid – NO3F, April 1935, DOI: https://doi.org/10.1002/ange.19350481604 [German paper]

It was first discovered by Cady that when fluorine is bubbled through 3 N nitric acid, then a remarkable compound, fluorine nitrate ($\ce{FNO3}$) is formed. It boils at -42 ℃ and is a very strong oxidizing agent and is capable of liberating iodine from iodides and in gaseous states, it explodes around 200-300 ℃.

References

  1. The reaction of Fluorine with Nitric acid and with solid Potassium Nitrate to form NO3F by Don M. Yost and Alan Beerbower, J. Am. Chem. Soc. April 1935, 57(4) 782. DOI: https://doi.org/10.1021/ja01307a520

  2. Prof. Dr. Otto Ruff, Dr. Walter Kwasnikie, Die Fluorierung der Salpetersäure. Das Nitroxyfluorid – NO3F, April 1935, DOI: https://doi.org/10.1002/ange.19350481604 [German paper]

It was first discovered by Cady that when fluorine is bubbled through $\pu{3 N}$ nitric acid, then a remarkable compound, fluorine nitrate ($\ce{FNO3}$) is formed. It boils at $\pu{-42 ^\circ C}$ and is a very strong oxidizing agent and is capable of liberating iodine from iodides and in gaseous states, it explodes around $\pu{200-300 ^\circ C}$.

References

  1. The reaction of Fluorine with Nitric acid and with solid Potassium Nitrate to form NO3F by Don M. Yost and Alan Beerbower, J. Am. Chem. Soc. April 1935, 57(4) 782. DOI: https://doi.org/10.1021/ja01307a520

  2. Prof. Dr. Otto Ruff, Dr. Walter Kwasnikie, Die Fluorierung der Salpetersäure. Das Nitroxyfluorid – NO3F, April 1935, DOI: https://doi.org/10.1002/ange.19350481604 [German paper]

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Nilay Ghosh
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It was first discovered by Cady that when fluorine is bubbled through 3 NN nitric acid, then a remarkable compound, fluorine nitrate ($\ce{FNO3}$) is formed. It boils at -42℃42 ℃ and is a very strong oxidizing agent and is capable of liberating iodine from iodides and in gaseous states, it explodes around 200-300℃300 ℃.

ReferenceReferences

  1. The reaction of Fluorine with Nitric acid and with solid Potassium Nitrate to form NO3F by Don M. Yost and Alan Beerbower THE REACTION OF FLUORINE WITH NITRIC ACID AND WITH SOLID POTASSIUM NITRATE TO FORM NO3F. , J. Am. Chem. Soc. April 1935, 57(4) 782. DOI: https://doi.org/10.1021/ja01307a520

  2. Prof. Dr. Otto Ruff, Dr. Walter Kwasnikie, Die Fluorierung der Salpetersäure. Das Nitroxyfluorid – NO3F, April 1935, DOI: https://doi.org/10.1002/ange.19350481604 [German paper]

It was first discovered by Cady that when fluorine is bubbled through 3 N nitric acid, then a remarkable compound, fluorine nitrate ($\ce{FNO3}$) is formed. It boils at -42℃ and is a very strong oxidizing agent and is capable of liberating iodine from iodides and in gaseous states, it explodes around 200-300℃.

Reference

  1. Don M. Yost and Alan Beerbower THE REACTION OF FLUORINE WITH NITRIC ACID AND WITH SOLID POTASSIUM NITRATE TO FORM NO3F. J. Am. Chem. Soc. April 1935, 57(4) 782. https://doi.org/10.1021/ja01307a520

  2. Prof. Dr. Otto Ruff, Dr. Walter Kwasnikie, Die Fluorierung der Salpetersäure. Das Nitroxyfluorid – NO3F, April 1935 https://doi.org/10.1002/ange.19350481604 [German paper]

It was first discovered by Cady that when fluorine is bubbled through 3 N nitric acid, then a remarkable compound, fluorine nitrate ($\ce{FNO3}$) is formed. It boils at -42 ℃ and is a very strong oxidizing agent and is capable of liberating iodine from iodides and in gaseous states, it explodes around 200-300 ℃.

References

  1. The reaction of Fluorine with Nitric acid and with solid Potassium Nitrate to form NO3F by Don M. Yost and Alan Beerbower, J. Am. Chem. Soc. April 1935, 57(4) 782. DOI: https://doi.org/10.1021/ja01307a520

  2. Prof. Dr. Otto Ruff, Dr. Walter Kwasnikie, Die Fluorierung der Salpetersäure. Das Nitroxyfluorid – NO3F, April 1935, DOI: https://doi.org/10.1002/ange.19350481604 [German paper]

Source Link
Nilay Ghosh
  • 26.8k
  • 27
  • 95
  • 205

It was first discovered by Cady that when fluorine is bubbled through 3 N nitric acid, then a remarkable compound, fluorine nitrate ($\ce{FNO3}$) is formed. It boils at -42℃ and is a very strong oxidizing agent and is capable of liberating iodine from iodides and in gaseous states, it explodes around 200-300℃.

Reference

  1. Don M. Yost and Alan Beerbower THE REACTION OF FLUORINE WITH NITRIC ACID AND WITH SOLID POTASSIUM NITRATE TO FORM NO3F. J. Am. Chem. Soc. April 1935, 57(4) 782. https://doi.org/10.1021/ja01307a520

  2. Prof. Dr. Otto Ruff, Dr. Walter Kwasnikie, Die Fluorierung der Salpetersäure. Das Nitroxyfluorid – NO3F, April 1935 https://doi.org/10.1002/ange.19350481604 [German paper]