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4
votes
1answer
24 views

How to derive the nuclear spin of 23Na?

Is it possible to derive the nuclear spin I=3/2 for $\ce{^23Na}$ from a term scheme or from something else from spectroscopy? I was asked this question in an old exam and didn't know how to do it. I ...
3
votes
1answer
34 views

Do electrons only fill 'spin up' first? Or could it start filling 'down spins' first?

Due to Hund's rule, electrons start filling up the orbitals without pairing up. When this is happening, do the electrons all fill up the 'up' spin? Could they fill in the 'down' spin? Why do they ...
1
vote
0answers
57 views

Co(H₂O)₆ , a low spin coordination complex,why?

Despite $\ce{H2O}$ being a weak field ligand, why is $\ce{[Co(H2O)6]^3+}$ a low spin complex?
5
votes
1answer
1k views

Total magnetic moment of atom

Whenever I read about coordination compounds in my textbooks, I always find a discussion about spin-only magnetic moment which is given by $\sqrt{n(n+2)}$ BM, Where $n$ is the number of unpaired ...
2
votes
1answer
105 views

Hund's rule & different $H_2$ molecules

Does Hund's rule allow both of the following scenarios? Filling each orbital with a single electron, so that a sub-shell, at first, only electrons with a negative spin Filling each orbital with a ...
22
votes
2answers
307 views

What is antisymmetric exchange? What is J-strain? Where does it come from?

I'm reading a paper1 by Sanakis, et al. that characterises the magnetic coupling in the $\ce{Fe3S4}$ clusters present in bacterial ferredoxin II and beef heart aconitase as arising through something ...
6
votes
4answers
462 views

Is the order of orientation of electron box diagrams meaningful or arbitrary?

Here is my interpretation when asked to: By drawing arrows in the appropriate boxes, complete the outer electron structures for Cu and Cu2+ I had no problem in drawing out the electron ...
10
votes
2answers
129 views

What makes a radical 'free'?

The qualifier 'free' seems to be ubiquitously attached to discussion of radicals as highly reactive species with unpaired spins. What, precisely (or imprecisely, as the case may be) does 'free' really ...
7
votes
1answer
280 views

Are there any examples of nuclear spin isomers having consequences for chemical reactivity?

Ortho- and parahydrogen are two forms of the $\ce{H2}$ molecule that are distinguished by their pairing or antipairing of nuclear spins, giving rise to metastable singlet (ortho-) and triplet (para-) ...