Hybridisation is the concept of mixing atomic orbitals to form new hybrid orbitals suitable for the qualitative description of atomic bonding properties.

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Are the bonding orbitals in methane equivalent - photoelectron spectrum

The low energy portion (the part dealing with the $\ce{2s}$ and $\ce{2p}$ electrons) of the photoelectron (PE) spectrum of methane is reproduced below. (image source) The reaction being examined ...
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166 views

What does it mean when it is said that an sp³ orbital has 25% s character?

My textbook frequently mentions: $\mathrm{sp^3}$ hybrid orbital has 25% $\mathrm{s}$-character and 75% $\mathrm{p}$-character. What are these "characters"? And how do these characters influence ...
6
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53 views

Change of electron spin in Carbon after Hybridization?

During bond formation in Carbon, one of the electrons from the 2s orbital jumps to one the empty p orbitals creating a hybrid orbital as seen in the figure below. Now clearly one electron from the ...
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42 views

On the geometry of sp3d and sp3d3 hybridization

A molecule in which the central atom is $sp^3d^2$ hybridized ($\ce{SF_6}$), for example, aquires an octahedral shape, which can be explained by assuming that the hybrid orbitals arrange themselves to ...
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1answer
102 views

Hybridization of Na in [Na(H2O)6]+

In the complex ion $\ce{[Na(H2O)6]+}$, the sodium cation forms 6 coordinate bonds with water ligands. Typically this octahedral form is associated with $sp^3d^2$ hybridization as far as I know, but in ...
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Is nitrogen of aniline sp² or sp³ hybridized? [duplicate]

I found a thread which discussed this which totally confused me. (refer to the part of the link which talks about $\ce{sp^2/sp^3}$) The question "How to rationalise the resonance structures and ...
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1answer
39 views

Length of C-H bonds in hybridized bonding orbitals

What is the effect of hybridization and double-bond formation on the rest of the atoms/molecules attached to the central atom? For example, in a benzene molecule, the Carbon-Carbon bonds are ...
2
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82 views

sp, sp2 and sp3 hybrid orbitals are actual solutions of Schrodinger's equation or only a heuristic?

According to Wikipedia's article about orbital hybridisation: [...] today it is considered an effective heuristic for rationalising the structures of organic compounds. [...] Hybrid orbitals are ...
6
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109 views

What is the hybridization of the carbonyl oxygen in a carboxylic acid?

My professor sent out a review guide. One of the questions on this guide is The carboxylic acid carbonyl oxygen is... A) $sp^2$ B) $sp^3$ C) H bond donor D) rapidly equilibrating between ...
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35 views

Why are the axial bonds of PF5 longer than those of the equatorial bonds? (Hybridization)

The axial bonds of $\ce{PF5}$ are longer than those of the equatorial positions. One explanation is that because the axial bonds are experiencing more repulsion than those of the equatorial and ...
3
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115 views

Understanding the hybridization of cyclohexane?

I'm having quite a fair bit of trouble comprehending the hybridization of cyclohexane. I understand that this is a ringed structure with single C-C bonds, therefore all the carbons should have sp3 ...
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24 views

How to identify reactions that change hybridization?

Usually looking at the reactions like the followings, e.g. addition of $\ce{Cl_2}$ to $\ce{PCl_3}$ to form $\ce{PCl_5}$ combustion of $\ce{CH_4}$ to produce $\ce{CO_2}$ I started by considering ...
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27 views

Order of priority in hybridization of d-orbitals

During hybridization of d-orbitals why the $d_{z^2}$ and $d_{x^2-y^2}$ orbitals are used up before the $d_{xy}$, $d_{yz}$ and $d_{zx}$ ?
5
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154 views

Hybridization of the oxygen in furan?

I fail to understand why the hybridization of oxygen in furan is $\ce{sp^2}$. I think that since there are 2 bond pairs and two lone pairs so it should be $\ce{sp^3}$ hybridized? Is it to do with the ...
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46 views

sp² hybridized orbital

I do not understand why and how an atom with $\ce{sp^2}$ hybridization has only one p orbital?? For example in pyridine why is the lone pair of nitrogen not counted as a pi electron.
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1answer
46 views

Why do electrons not get paired up in [Fe(H2O)5NO]2+?

The magnetic moment of [Fe(H2O)5NO]2+ is 3.87 Bohr magneton, which implies there are 3 unpaired electrons. Since iron is in +1 oxidation state (due to charge transfer with nitrosyl group), it's ...
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288 views

Why are sp hybridized carbocations high energy?

You don’t see carbocations on double bonds very much, and here’s a good reason: compared to sp3, there is more s character in the orbitals, so the empty orbital is held more closely to the ...
3
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1answer
93 views

Electron Pair Geometry in Ibuprofen (Electron Pair Geometry in Organic Compounds)

I am trying to determine the electron pair geometry (and molecular geometry) of some atoms in ibuprofen. The first one I am trying to do is the double bonded oxygen. Ibuprofen is pictured below: I ...
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1answer
94 views

Hybridization - Mixing one atomic s orbital with 2p orbitals

Explain why three ${sp^2}$ hybrid orbitals result when one s atomic orbital is blended with two p atomic orbitals.
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55 views

Structure of XeF4 [closed]

How can we get the structure of $Xe F_{4}$ using the concept of hybridization and number of lone pairs.
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1answer
37 views

Determine which orbitals will form hybrids with one another

I've been teaching myself chemistry, so any help is greatly appreciated. I've been reading an online tutorial that claims the two orbitals that merge in Aluminum trihydride are 1 orbital of 2s and 2 ...
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1answer
101 views

Determine the bond angle in a compound [closed]

How can we find the bond angle between 3 atoms in a compound? Please specify an equation which can be used for all compounds.
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1answer
364 views

Hybridization in azide ion?

In the azide ion, there is a symmetrical arrangement of three nitrogen atoms. If I've been told to figure out the hybridization of each nitrogen atom, what's the best way to go about doing this? My ...
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1answer
64 views

What is lowest energy state, how does an atom gain it and what does it have to do with hybridization?

I understand that hybridisation occurs due to the atom wanting to exist in the most stable state possible, and the most stable state has the lowest energy. What I don't understand, however, is say, in ...
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1answer
185 views

Why hybridization occurs in diatomic molecule

In diatomic nitrogen There are two electron configurations I'd like to compare: 1s2 2s2(lone pair) 2p3(the bonding electrons sigma,pi,pi) 1s2 2sp(lone pair) 2sp(sigma bonding) 2p2(pi,pi bonding) ...
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116 views

Doesn't the fact that the lone pair on the nitrogen in amides occupy a p orbital contradict Hund's rules?

Since the $\ce{sp^2}$ hybridized orbitals are lower in energy than the p orbital shouldn't the $\ce{sp^2}$ orbitals fill first? Why is this not the case - two electrons fill the p orbitals while all ...
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194 views

Why F replaces axial bond in PCl₅?

Why does $\ce{F}$ replace an axial bond in $\ce{PCl5}$? I realize that it would be more stable there than at equatorial bond, but what is the reason of its stability? Similarly in $\ce{AB4}$ type of ...
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37 views

Explanation of Bent's Rule [duplicate]

Why does the %s character increase on the orbital with electropositive atom? I do not seem to properly grasp this concept. Is this rule based on observation or is there any proof to it? If there is a ...
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61 views

Hybridised orbitals

What determines which type of hybridisation (sp3/sp2/sp) a molecule will take? Methane/ethylene/acetylene all have the same electron configuration but undergo different different types of ...
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118 views

Type of hybridisation

State the hybridisation of asterisked carbon in $\ce{CH3 - CH = C^{✪} = CH2}$ I am not sure between $sp^2$ and $sp$ hybridization. Because of double bond I think it should be $sp^2$ but because of 2 ...
2
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1answer
122 views

Bent's rule for Sulfur trioxide and Sulfur dioxide

How is Bent's rule applied on $\ce{SO3}$ and $\ce{SO2}$? Bond length of $\ce{SO3}$ < $\ce{SO2}$. Is this a direct consequence of applying the Bent's rule?
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Carbon atoms at the edge of a diamond

It is well known (the simplest textbook example) that a diamond has a well-defined arrangement of sp3 carbon atoms, as each atom is connected to four others in a ...
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557 views

Why is one lobe of an sp3 hybridized orbital smaller than its other half?

A hybrid sp3 orbital is drawn with one lobe smaller than its other half, the latter which is of equal size when drawing the p orbital. Why is it so?
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What is Bent's rule?

I'm all bent out of shape trying to figure out what Bent's rule means. I have several formulations of it, and the most common formulation is also the hardest to understand. Atomic s character ...
11
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Why does bond angle decrease in the order H₂O, H₂S, H₂Se?

I know that bond angle decreases in the order $\ce{H2O}$, $\ce{H2S}$ and $\ce{H2Se}$. I want to know the reason. I think this is because lone pair repulsion but how?
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Hybridization in PH3

Does $\ce{PH3}$ exhibit $\ce{sp^3}$ hybridization? Arguments against hybridization: $\ce{PH3}$ is less basic than $\ce{NH3}$. This jibes with the supposition that $\ce{PH3}$ keeps its lone pair ...
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Do filled Orbitals also hybridize?

Recently I was watching a video on Valence Bond Theory, on the MIT Open-Course youtube channel. The teacher there said that for hybridization to occur, electron promotion from fully filled orbitals to ...
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What is the origin of the differences between the MO schemes of O₂ and N₂?

Here are the MO schemes of $\ce{N2}$ (left) and $\ce{O2}$ (right). Why is the $\sigma$-MO formed by the $p$ AOs energetically above the $\pi$-MO for $\ce{N2}$ but not for $\ce{O2}$? Can it be ...
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Does hybridization take place in other atoms apart from central atom in a molecule?

I have seen my textbooks always give formula and description of hybridization of central atom of a molecule.But I wonder will other atoms present(not Hydrogen) go in hybridization or only the central ...
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Nitric acid vs. chloric acid strength

Here the central chlorine atom is best described as $\ce{sp^3}$ hybridized. This makes sense; the molecule is pyramidal. Also, due to the molecule's pyramidal geometry, this rules out the ...
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Are ther known compounds of Argon? What is their molecular geometry and hybridisation?

Can Argon hybridize orbitals and/or form covalent-like/ionic-like compounds? Is there any study of that? I would be happy to read concrete references. What kind of molecular geometries for argon ...
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252 views

Determining central atom in NCl3

Less electronegative atom is the central atom. $\ce{N}$ is more electronegative than $\ce{Cl}$ as $\ce{Cl}$ has larger atomic radius. So why in $\ce{NCl3}$, $\ce{N}$ is the central atom?
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68 views

Hybridization in Light of Resonance

According to this video: http://www.youtube.com/watch?v=ns4Py96Bkn8&NR=1 1) Is this true? (You might recall I asked a similar question about $\ce{sp^2}$ hybridization implying $\ce{sp^2}$ ...
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250 views

sp3 hybridisation in carbon

Before $\ce{sp^3}$ hybridisation, does the $\ce{C}$ -atom get excited to $\ce{1s^2~2s^1~2p^3}$ state, as it happens before $\ce{sp^2}$ hybridisation? What is the energy of the $\ce{sp^3}$ hybridised ...
3
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3answers
867 views

PI Bonding in Carbon Dioxide

I am fairly sure the first diagram I drew for carbon dioxide is wrong in terms of showing pi bonding. This is because we use a pi orbital twice, which isn't possible. The second diagram corrects this ...
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Is this textbook bonding picture of hybridization in ethene wrong?

Regarding the above picture, why is the $\ce{C-C}$ $\sigma$ bond composed of two $\ce{sp^2}$ orbitals while the $\ce{C-H}$ $\sigma$ bonds composed of $\ce{sp^3}$ hybrid orbitals? I don't see why; I ...
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Why does sp2 hybridization imply adjacent sp2 hybridization?

EDIT: I misquoted my teacher; he said something more along the lines of: in conjugated systems, if an atom is $\ce{sp^2}$ hybridized, then every atom it is bound to is also $\ce{sp^2}$ hybridized. ...
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Why does ammonia have sp hybridization?

Apparently it has $sp^3$ hybridization, but I don't understand why. Ammonia ($\ce{NH3}$) seems to me to not require $sp$ hybridization because all of its bond lengths are already equal. It has 3 ...
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Does the hybridization model gives us any further insight on Molecular Geometry?

It doesn't seem as though the hybridization model adds anything useful to the discussion of molecular geometry as predicted by the VSEPR model. It's just another way of labeling linear, trigonal ...
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Is hybridization used in ab-initio valance bond calculation?

Many general chemistry textbooks introduced the concept "hybridization" to construct a symmetry-adapted VB-type wavefunction. In the textbooks, usually the minimal basis is used and without optimizing ...