Take the 2-minute tour ×
Chemistry Stack Exchange is a question and answer site for scientists, academics, teachers and students. It's 100% free, no registration required.

In the reaction of combustion of gunpowder,

Sulfur is used to speed up the reaction and acts like a catalyst in that it increases the rate of reaction. However, unlike a catalyst, it is used up in the reaction.

I understand that transition metals are often used as catalysts but why can sulphur act like a catalyst?

share|improve this question
add comment

1 Answer 1

It's not a catalyst here. It speeds up the reaction, which is why it acts like a catalyst.

Here is the reaction without sulphur:

$\ce{6 KNO3 + C7H8O -> 3 K2CO3 + 4 CO2 + 2 H2O + 3 N2}$

And here it is with sulphur:

$\ce{4 KNO3 + C7H4O + 2 S —> 2 K2S + 4 CO2 + 3 CO + 2 H2O + 2 N2}$

(Source)

Sulphur decreases the ignition temperature, as well as probably contributing a bit to the rate. Here, it is effectively turning $\ce{CO2}$ amd $\ce{K2CO3}$ to $\ce{CO}$ and $\ce{K2S}$. If you take into account Le Chatelier's principle, the conversion of the products of the basic reactants speeds it up. (The decrease in concentrations/activities of the products due to their conversion means that the equilibrium shifts in the forward direction to compensate for it.)

So it is speeding up the reaction and making it easier to carry out. Not a catalyst.

A note: There's no reason why any element/compound can't act as a catalyst. Transition metals are generally catalysts in a certain type of reaction, and they generally catalyze the reaction by adsorbing the gases. Catalysts can work in many other ways—generally they form intermediates in the reaction, and present an alternative path via the intermediate. ($\ce{V2O5}$, for example, is a catalyst in many reactions involving organic compounds, since it forms cyclic intermediates with various groups).

share|improve this answer
    
Can you elaborate on how Le Chateleir's principle comes in? I didn't get that part :-) –  Brian Feb 17 '13 at 15:08
    
@Brian: done. I'm not really sure if it has an effect here, though. It may just be a thermodynamic phenomenon. –  ManishEarth Feb 17 '13 at 15:17
add comment

Your Answer

 
discard

By posting your answer, you agree to the privacy policy and terms of service.

Not the answer you're looking for? Browse other questions tagged or ask your own question.